Course Title : Physical Organic Chemistry

Code 10H808
Course Year Master and Doctor Course
Class day & Period Thu 2nd
Location A2-308
Lecture Form(s) Lecture
Language Japanese
Instructor Kenji Matsuda

Course Description

Properties of organic compounds, such as electric conductivity, magnetism, photophysical properties, are discussed in terms of molecular structure and electronic structure



Course Goals

To understand principles of photochemistry

Course Topics

Theme Class number of times Description
Photochemical Reaction 1 Photochemistry, Photophysics, einstein (unit), Jablonski diagram, Excitation, Internal conversion, Intersystem crossing, Fluorescence, Phosphorescence, Photochemical reaction
Excited States in Molecular Orbital Theory 2 Born-Oppenheimer approximation, Flanck-Condon principle, Singlet, Triplet, Energy gap, n-pi*, pi-pi*, Potential energy surface, Conical intersection, Solvatochromism
Electronic Transition 2 Transition probability, Fermi's golden rule, Transition moment, Oscillator strength, Polarized light, Stimulated emission, Einstein coefficient, Beer-Lambert law, Selection rule, Spin-orbit coupling
Radiative Transition 2 Fluorescence, Phosphorescence, Fluorescence excitation spectrum, Mirror relationship, Vibrational structure, Fluorescence quantum yield, Emission rate constant
Behavior of 2 Energy Transfer, Quenching, Trivial, Foerster, Dexter, FRET, Stern-Volmer plot, Excimer, Exciplex, Triplet sensitization
Phororeaction, Photoisomerization 2 Quantum yield, Photochromism, Conversion in photoisomerization




Independent Study Outside of Class

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